Consider the following chemical equilibrium: N2 (g) + 3H2 ⇌ 2NH3

Now write an equation below that shows how to calculate Kp from Kc for this reaction at an absolute temperature .

Kp = Kc (RT) ^(-2)

Explanation:

For the reaction;

N2 (g) + 3H2 ⇄ 2NH3(g)

We can write;

Kc = [NH3]^2/[N2] [H2]^3

But

Kp = pNH3^2/pN2 . PH2^3

To convert from Kc to Kp

Kp = Kc (RT) ^Δn

where Δn is the change in number of moles going from reactants

to products.

For this reaction;

Δn = 2- (3+1) = -2

Kp = Kc (RT) ^(-2)

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answer : third trial had the contaminated sample and the correct value for dhrxn should be 1000 kj/mol

explanation :

let us write down the given equations

equation 1 :

equation 2 :

equation 3 :

let us use hess's law to find out which 2 equations can be added to get the third equation.

let us reverse equation 2 and multiply it by 2. the new equation that we get is,

equation 4 :

let us add equation 1 & 4

the above equation is similar to equation 3 but has different value for dhrxn.

therefore third trial had the contaminated sample and the correct value for dhrxn should be 1000 kj/mol