Please help this is chemistry.

Gymnast always perform on padded mats. how does the mats protect the gymnast

Assuming complete dissociation of the solute, how many grams of kno3 must be added to 275 ml of water to produce a solution that freezes at -14.5 c? the freezing point for pure water is 0.0 c and k_f is equal to 1.86 c/m

How many moles of lead are in 1.50 x 10^12 atoms of lead? could you explain the answer as well and not just give it to me i am refreshing for finals and i need to know how to do it