Given the data: Ag2O(s), = ‑31.1 kJ mol-1, S° = +121.3 J mol-1 K-1 Ag(s), = 0.00 kJ mol-1, S° = +42.55 J mol-1 K-1 O2(g), = 0.00 kJ mol-1, S° = +205.0 J mol-1 K-1 Calculate the temperature at which = 0 for the reaction, Ag2O(s) → 2 Ag(s) + ½ O2(g). Assume that, since the physical states do not change, and are independent of tempera­ture between ‑50.0 °C and 950.0 °C.

Explanation:

Hello,

In this case, for the given decomposition reaction, we can compute the enthalpy of reaction considering the enthalpy of formation of each involved species (products minus reactants):

Next, the entropy of reaction considering the standard entropy for each involved species (products minus reactants):

Next, since the Gibbs free energy of reaction is computed in terms of both the enthalpy and entropy of reaction at the unknown temperature, for such Gibbs energy equaling 0, the temperature (in K and °C) turns out:

Which is within the given rank.

Best regards.

he uptake of drugs from the intestine is often strongly influenced by diffusion. for example, consider a water-insoluble steroid for treating inflammation that is solubilized in aggregates of detergent molecules, called micelles. these micelles, aggregates of 80 soap molecules, have a molecular weight of 24,000, a diameter of 2.6 nm, and a charge of -27. the positively charge ions (counterions) in this system are na".