Determine the molar solubility (S) of Ag2CO3 in a buffered solution with a pH of 4.207 using the systematic treatment of equilibrium. Ksp(Ag2CO3) = 8.46 × 10–12; Ka1(H2CO3) = 4.45 × 10–7; Ka2(H2CO3) = 4.69 × 10–11.

Given Hint: Use the systematic treatment of equilibrium to solve this problem. 1. Write the pertinent reactions. 2. Write the charge balance equation. 3. Write the mass balance equations. 4. Write the equilibrium constant expressions for each reaction. 5. Count the equations and unknowns. 6. Solve for all unknowns.