1. Write an expression for the energy of a single electron in a hydrogen-like orbit. Your expression should take into account a nuclear charge of Z and quantum number n. (b) Express your answer in Hartrees if the electron is in a hydrogen 1s orbital. (c) Calculate the energy in Hartrees of an electron in a helium 1s and a helium 2s orbital, neglecting the electron-electron repulsion term in the Hamiltonian.

Aheat engine running backward is called a refrigerator if its purpose is to extract heat from a cold reservoir. the same engine running backward is called a heat pump if its purpose is to exhaust warm air into the hot reservoir. heat pumps are widely used for home heating. you can think of a heat pump as a refrigerator that is cooling the already cold outdoors and, with its exhaust heat qh, warming the indoors. perhaps this seems a little silly, but consider the following. electricity can be directly used to heat a home by passing an electric current through a heating coil. this is a direct, 100% conversion of work to heat. that is, 19.0 \rm kw of electric power (generated by doing work at the rate 19.0 kj/s at the power plant) produces heat energy inside the home at a rate of 19.0 kj/s. suppose that the neighbor's home has a heat pump with a coefficient of performance of 4.00, a realistic value. note: with a refrigerator, "what you get" is heat removed. but with a heat pump, "what you get" is heat delivered. so the coefficient of performance of a heat pump is k=qh/win. an average price for electricity is about 40 mj per dollar. a furnace or heat pump will run typically 200 hours per month during the winter. what does one month's heating cost in the home with a 16.0 kw electric heater? what does one month's heating cost in the home of a neighbor who uses a heat pump to provide the same amount of heating?

9.98 kg of r-134a at 300 kpa fills a rigid container whose volume is 14 l. determine the temperature and total enthalpy in the container. the container is now heated until the pressure is 600 kpa. determine the temperature and total enthalpy when the heating is completed. use data from the steam tables.

Acarpenter builds an exterior house wall with a layer of wood 2.9 cm thick on the outside and a layer of styrofoam insulation 2.3 cm thick on the inside wall surface. the wood has k=0.080w/(m⋅k), and the styrofoam has k= 0.010 w/(m⋅k). the interior surface temperature is 19.0 ∘c , and the exterior surface temperature is -15.0 ∘c . a.)what is the temperature at the plane where the wood meets the styrofoam? celsius b.)what is the rate of heat flow per square meter through this wall? /m^2