HELP pleaseee which nucleus completes the following equation?

May someone explain how to do this question?

Because air contracts as it cools, the air pressure inside a freezer is typically lower than on the outside. why do ice cubes inside a freezer tend to shrink over time? a. the ice dissolves oxygen from the air, forming a denser crystalline matrix.b. the ice reacts chemically with carbon dioxide in the air, forming gaseous carbon compounds.c. the ice melts, and then the liquid freezes as ice crystals on the bottom of the freezer.d. the ice sublimes, and then the water vapor deposits as ice crystals on the sides of the freezer.

Light traveling in water, nwater = 1.33, strikes a plastic block at an angle of incidence of 51.4°; part of the beam is reflected and part is refracted. if the index of refraction of the plastic is 2.0, what is the angle made by the reflected and refracted beams?