Please help I’ve been stuck all morning

Identify the arrows that show the correct direction of heat transfer. 66°f 112°f 98°f

Calculate the heat capacity per object when the total energy is 4 quanta. (think of this in terms of increasing from 3.5 quanta of energy in the system to 4.5 quanta of energy in the system, if that were possible.) c4 = __ j/k/object

Modern physics a photon emitted from an excited hydrogen atom has an energy of 3.02 electron volts. which electron energy-level transition would produce this photon? a. n=1 to n=6 b. n=2 to n=6 c. n=6 to n=1 d. n=6 to n=2 i chose b but the correct answer is d can someone tell me why? and what's the difference?