Need help with question 1) and 2) please ASAP ??? 15 points ?

Consider the particle-in-a-box problem in 1d. a particle with mass m is confined to move freely between two hard walls situated at x = 0 and x = l. the potential energy function is given as (a) describe the boundary conditions that must be satisfied by the wavefunctions ψ(x) (such as energy eigenfunctions). (b) solve the schr¨odinger’s equation and by using the boundary conditions of part (a) find all energy eigenfunctions, ψn(x), and the corresponding energies, en. (c) what are the allowed values of the quantum number n above? how did you decide on that? (d) what is the de broglie wavelength for the ground state? (e) sketch a plot of the lowest 3 levels’ wavefunctions (ψn(x) vs x). don’t forget to mark the positions of the walls on the graphs. (f) in a transition between the energy levels above, which transition produces the longest wavelength λ for the emitted photon? what is the corresponding wavele

An ideal gas is held in a container at constant volume. initially, its temperature is 5 degrees c and its pressure is 1.2 atm. what is its pressure when its temperature is 43 degrees c? answer in units of atm

Calculate the ratio of h+ ions to oh– ions at a ph = 6. find the concentration of h+ ions to oh– ions listed in table b of your student guide. then divide the h+ concentration by the oh– concentration. record this calculated ratio in table a of your student guide. compare your approximated and calculated ratios of h+ ions to oh– ions at a ph = 6. are they the same? why or why not? record your explanation in table a. what is the concentration of h+ ions at a ph = 6? mol/l what is the concentration of oh– ions at a ph = 6? mol/l what is the ratio of h+ ions to oh– ions at a ph = 6? : 1