The coupling constant (J) for bromoethane is 7 Hz when the 1H NMR spectrum is acquired at 250 MHz. What is the coupling constant between these protons when the spectrum is acquired at 500 MHz?

Two horizontal plates with infinite length and width are separated by a distance h in the z direction. the bottom plate is moving at a velocity u. the incompressible fluid trapped between the plates is moving in the positive x-direction with the bottom plate. align gravity with positive z. assume that the flow is fully-developed and laminar. if the systems operates at steady state and the pressure gradient in x-direction can be ignored, do the following: 1. sketch your system 2. identify the coordinate system to be used. 3. show your coordinates and origin point on the sketch. list all your assumptions. 5. apply the continuity equation to your system. nts of navier stokes equations of choice to your system 7. solve the resulting differential equation to obtain the velocity profile within the system make sure to list your boundary conditions. check units of velocity 8. describe the velocity profile you obtain using engineering terminology. sketch that on the same sketch you provided in (1). 9. obtain the equation that describes the volumetric flow rate in the system. check the units.

In a thunderstorm, charge builds up on the water droplets or ice crystals in a cloud. thus, the charge can be considered to be distributed uniformly throughout the cloud. for the purposes of this problem, take the cloud to be a sphere of diameter 1.00 kilometer. the point of this problem is to estimate the maximum amount of charge that this cloud can contain, assuming that the charge builds up until the electric field at the surface of the cloud reaches the value at which the surrounding air breaks down. this breakdown means that the air becomes highly ionized, enabling it to conduct the charge from the cloud to the ground or another nearby cloud. the ionized air will then emit light due to the recombination of the electrons and atoms to form excited molecules that radiate light. in addition, the large current will heat up the air, resulting in its rapid expansion. these two phenomena account for the appearance of lightning and the sound of thunder. take the breakdown electric field of air to be eb=3.00ă—106n/c. part a estimate the total charge q on the cloud when the breakdown of the surrounding air is reached. express your answer numerically, to three significant figures, using ďµ0=8.85ă—10â’12c2/(nâ‹…m2) .

Which body part transports oxygen removes waste materials in carries nutrients to the body as part of the circulatory system