What are roots made out of

Acar tire contains 0.0380 m^3 3 of air at a pressure of 2.20 ×10^{5} 5 n/m^2 2 (about 32 psi). how much more internal energy does this gas have than the same volume has at normal atmospheric pressure, 1.01x10^5 5 pa?

Ammonia enters the expansion valve of a refrigeration system at a pressure of 10 bar and a temperature of 18oc and exits at 6.0 bar. the refrigerant undergoes a throttling process. determine the temperature, in oc, and the quality of the refrigerant at the exit of the expansion valve.

If y gets smaller as x gets bigger and y have an relationship?