Help 2 questions 20 points!

Pls , the question is in the picture!

The ratio pv to nrt is plotted against pressure for ch4 at 0°c and 200°c. why does the curve for 0°c drop below the horizontal line for an ideal gas whereas the curve for 200°c does not?

In a sample of 200 residents of georgetown county, 120 reported they believed the county real estate taxes were too high. develop a 95 percent confidence interval for the proportion of residents who believe the tax rate is too high. (round your answers to 3 decimal places.) confidence interval for the proportion of residents is up to . would it be reasonable to conclude that the majority of the taxpayers feel that the taxes are too high?