Please and this quickly and no links please

The ratio pv to nrt is plotted against pressure for ch4 at 0°c and 200°c. why does the curve for 0°c drop below the horizontal line for an ideal gas whereas the curve for 200°c does not?

Awoman has 14 different shirts: 10 white shirts and 4 red shirts. if she randomly chooses 2 shirts to take with her on vacation, then what is the probability that she will choose two white shirts? show your answer in fraction and percent, round to the nearest whole percent.

Johnny rode his bike to a friends house 4 blocks down the street in his neighborhood. he immediately rode back home once he realized his friend was unable to play. what was his displacement for the total bike ride trip? what could you use as a reference point ? show the steps to solve this problem.