How solve.

Apiston-cylinder with a volume of 0.25 m3 holds 1 kg of air (r 0.287 k/kgk) at a temperature of 100 c. heat transfer to the cylinder causes an isothermal expansion of the piston until the volume triples. how much heat is added to the piston-cylinder?

Apipe with an outside diameter of 15 cm is exposed to an ambient air and surrounding temperature of -20°c. the pipe has an outer surface temperature of 65°c and an emissivity of 0.85. if the rate of heat loss from the pipe surface is 0.95 kw per meter of length, the external convective heat transfer coefficient (h) is: (a) 12.5 w/m"k (b) 18.6 w/mk (c) 23.7 w/mk (d) 27.9 w/mk (e) 33.5 w/mk

What is the heat treatment of metals? what is the benefit of it? why and how it's useful? answer in details, do not write by hand.