The standard reaction enthalpy for the decomposition of CaCl2 · NH3(s) into CaCl2(s) and NH3(g) is nearly constant at +78 kJ mol−1 between 350.K and 470.K. The equilibrium pressure of NH3 in the presence of CaCl2 · NH3 is 1.71 kP a at 400.K. Find an expression for the temperature dependence of ∆rG◦ m in the same range.

Estimate the change in specific internal energy au and specific enthalpy h from inlet to outlet for ethylene glycol (a liquid) flowing through each of the following devices: (a) a heat exchanger where the glycol temperature increases from 20 °c to 80 °c; (b) a pump operating at about 25 °c and increasing the glycol pressure from 100 kpa to 8 mpa.

At steady state, air at 200 kpa, 325 k, and mass flow rate of 0.5 kg/s enters an insulated duct having differing inlet and exit cross-sectional areas. the inlet cross-sectional area is 6 cm2. at the duct exit, the pressure of the air is 100 kpa and the velocity is 250 m/s. neglecting potential energy effects and modeling air as an 1.008 kj/kg k, determine ideal gas with constant cp = (a) the velocity of the air at the inlet, in m/s. (b) the temperature of the air at the exit, in k. (c) the exit cross-sectional area, in cm2

To save energy, the air supply to a 2000 ft office has been shut off overnight and the room temperature has dropped to 40°f. in the morning, the thermostat is reset to 70°f and warm air at 120 f begins to flov in at 200ft'/min. the air is well mixed within the room, and an equal mass flow of air at room temperature (changing with time) is withdrawn through a return duct. the air pressure is nearly 1 atm everywhere. ignoring heat transfer with the surroundings and kinetic and potential energy effects, estimate how long it takes for the room temperature to reach 70°f. plot the room temperature as a function of time.