An ammonium buffer solution is prepared by combining 50. mL of 0.20 M ammonia, NH3(aq), and 50. mL of 0.20 M of ammonium chloride, NH4Cl(aq). A 5.0 mL sample of 0.10 M HCl(aq) is added to the buffer solution. Which of the following is a correct pairing of the ammonium species present in greater concentration and of the pH of the solution after the HCl(aq) is added? (The pKb of ammonia is 4.7.)

(A) NH3 < 9.3
(B) NH3 > 9.3
(C) NH4+ < 9.3
(D) NH4+ > 9.3

the answer is b. dilution

hydrocarbons are organic compounds that contain only hydrogens and carbons. they can be saturated (those which contain only carbon-carbon single bonds) or unsaturated (those which contain carbon-carbon double or triple bonds) in nature. hydrocarbons can undergo several reactions like substitution, elimination etc.  

on substituting one or more hydrogen atoms in hydrocarbon it results in the formation of haloalkane. as the halogen atoms are large compared to the carbon and hydrogen atoms, due to which the molecular weight increases and the bond become polar because of presence electronegative halogen atom and results in the increase in boiling point of the haloalkane.

thus, the correct option is (b) that is the boiling point of the new compound increases on substituting a hydrogen atom with a halogen in a hydrocarbon.