A farmer applies 1705 kg of a fertilizer that contains 10.0% nitrogen to his fields each year. Fifteen percent (15.0%) of the fertilizer washes into a river that runs through the farm. If the river flows at an average rate of 0.345 cubic feet per second, what is the additional concentration of nitrogen (expressed in milligrams of nitrogen per liter) in the river water due to the farmer's fertilizer each year?

There are two steps in the usual industrial preparation of acrylic acid, the immediate precursor of several useful plastics. in the first step, calcium carbide and water react to form acetylene and calcium hydroxide: cac2 (s) + 2h2o (g) → c2h2 (g) + caoh2 (s) =δh−414.kj in the second step, acetylene, carbon dioxide and water react to form acrylic acid: 6c2h2 (g) + 3co2 (g) + 4h2o (g) → 5ch2chco2h (g) =δh132.kj calculate the net change in enthalpy for the formation of one mole of acrylic acid from calcium carbide, water and carbon dioxide from these reactions. round your answer to the nearest kj .