CH3OH(g) → CO(g) + 2 H2(g) The reaction represented above goes to completion. The reaction takes place in a rigid, insulated vessel that is at 600 K.

A sample of CH3OH(g) is placed in the previously evacuated vessel with a pressure of P₁ at 600 K. What is the final pressure after the reaction is complete and the contents of the vessel are returned to 600 K?

so here we go

atomic mass

239 + 1 = y + 134 + 3 combine like terms

240 = y + 137             subtract 137 from both terms

240 - 137 = y

103 = y

atomic number

94 = z +54 + 0

94 = z + 54               subtract 54 from both sides.

40 = z

answer

atomic mass = 39

number of neutrons = 20

number of protons= 19

electronic configuration = 1s2 2s2 2p6 3s2 3p6 4s1

the number of electron in first shell = 2

number of electrons in n=3 shell = 8

answer : (a) volume of the gas = 8.67 ×   l

                (b) second virial coefficient b = -1.21226 l/mole

solution :   given,     t = 300k

                                p = 20atm

                                z = 0.86

                                n = 8.2 mmoles = 8.2 × moles

                                r =   0.082 l atm/k/mol

        find,     (a) volume of gas   and (b) second virial coefficient b at 300k.

formula used :            

                          and            

(a)            

                    = \times 0.082\times 300}{20}[/tex]

                    = 8.67 ×   l

(b)      

                    = (0.00867-1) × 8.659

                    = - 8.5839 l/mole