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If you add 10ml of hot water to 10ml of cold water and the change in tempature 8°c calculate how much energy is gained by the cold water

If i initially have a gas at a pressure of 12 atm, a volume of 23 liters, and a temperature of 200 k, and then i raise the pressure to 14 atm and increase the temperature to 300 k, what is the new volume of the gas?

If you add 5.00 ml of 0.100 m sodium hydroxide to 50.0 ml of acetate buffer that is 0.100 m in both acetic acid and sodium acetate, what is the ph of the resulting solution? acetic acid: ka = 1.8. x 10-5