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Chemistry, 02.12.2021 19:00 sullydai6510

You are titrating 45.0 mL of 0.0100 M Sn2+ in 1 M HCl with 0.0500 M Tl3+ resulting in the formation of Sn4+ and Tl+. A Ptindicator electrode and a saturated Ag|AgCl reference electrode are used to monitor the titration. What is the balanced titration reaction?

titration reaction:

⟢

1. Complete the two half‑reactions that occur at the Pt indicator electrode. Write the half-reactions as reductions.

half-reaction:

Sn+eβˆ’β†½βˆ’βˆ’β‡€

∘=0.139 V

half-reaction:

Tl+eβˆ’β†½βˆ’βˆ’β‡€

∘=0.77 V

2. Select the two equations that can be used to determine the cell voltage at different points in the titration. of the saturated Ag|AgCl reference electrode is 0.197 V.

a. =0.139βˆ’0.05916log([Sn2+][Sn4+])βˆ’0.1 97

b. =0.139βˆ’0.05916log([Sn4+][Sn2+])βˆ’0.1 97

c. =0.139βˆ’0.059162log([Sn4+][Sn2+])βˆ’0. 197

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You are titrating 45.0 mL of 0.0100 M Sn2+ in 1 M HCl with 0.0500 M Tl3+ resulting in the formation...
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