2. Calculate the heat of combustion of C6H14(l) in kJ/mol if 1.66 g of C6H14(l) were ignited in a calorimeter containing 2750. g H2O. A 3.54˚C temperature rise was observed. The calorimeter constant is 11.2 kJ/˚C. The specific heat of water is 4.184 J/g˚C.

c is having 4 valence electrons and is bonded to three hydrogens and one sulphur atom, therefore, the number of bond pair is equal to four. as all the valence electrons are used in forming the bonds so, there is no lone pair left on carbon.

s is having 6 valence electrons and is bonded to one other sulfur atom and one carbon atom, therefore, the number of bond pair is equal to 2. as only two valence electrons are used in forming the bonds so, four electrons are left. therefore, two lone pairs are present on s.