Explain why boiling is a reversible change

This is a reversible change. Similarly, if you boil water, it evaporates and becomes water vapor. When you cool this vapor down, it turns back to water. A change which cannot happen backward, that is, it cannot be reversed is called an irreversible change.

Explanation:

When we boil water by heating, then it changes into steam. Now, if we cool the steam, then water is formed again. So, the changing of water into steam has been reversed by cooling. Thus, the boiling of water (or evaporation of water) is a reversible change.

in the given question, the partial pressure is calculated by using the ideal gas equation, that is, pv = nrt

here, p is pressure, v is volume = 25 l, n is number of moles = 0.0104 moles, r is gas constant = -0.0821 l.atm / mol.k

t is temperature = 273 k

p = nrt / v

p = (0.0104 mol × 0.0821 l.atm / mol.k × 273 k) / 25 l

= 0.0093 atm