What did werner heisenberg discover about the atom

Match the mixture with the substance// i really need on this guys (it’s a pic btw)

A5 mole sample of liquid acetone is converted to a gas at 75.0°c. if 628 j are required to raise the temperature of the liquid to the boiling point, 15.600 kj are required to evaporate the liquid, and 712 j are required to raise the final temperature to 75.0°c, what is the total energy required for the conversion?

Salt in oceans comes from and of rocks