Help me plsss yall?

Large helium-filled balloons are used to lift scientific equipment to high altitudes. what is the pressure inside such a balloon if it starts out at sea level with a temperature of 10.0ºc and rises to an altitude where its volume is twenty times the original volume and its temperature is – 50.0ºc ?

Acalorimeter is to be calibrated: 51.203 g of water at 55.2 degree c is added to a calorimeter containing 49.783 g of water at 23.5c. after stirring and waiting for the system to equilibrate, the final temperature reached is 37.6 degree c. specific heat capacity of water (s = 4.18 j/g∙degree c). calculate the calorimeter constant. (smδt)warm water = -[(smδt)cold water + (calorimeterδtcold water)]

How many liters of ethylene glycol antifreeze (c2h6o2), with a density of 1.100 g/l, would you add to your car radiator containing 15.0 kg of water if you needed to protect your engine to - 21.5°c? for water, kf = 1.86°c m -1.