Calculate the mass in grams of 3.10x1023 molecules of water

Yes it would be a physical change.

Fine out you self hx

The internal energy of the system we can term it as total potential energy and kinetic energy. energy flows out of the surrounding from the system then we can say that the internal energy of the final state is lower than its initials. the sign of  δesystem is negative.δesystem = efinal - einitial=-ve  efinal  ∠einitial.