In modeling solid-state structures, atoms and ions are most often modeled as spheres. A structure built using spheres will have some empty, or void, space in it. A measure of void space in a particular structure is the packing efficiency, defined as the volume occupied by the spheres divided by the total volume of the structure. Given that a solid crystallizes in a body centered cubic structure that is 3.12 Å on each side, answer questions (a)-(e). (1 Å = 1 10-10 m.) (a) How many total atoms are there in each unit cell? atom(s) (b) What is the volume of one unit cell in Å3? WebAssign will check your answer for the correct number of significant figures. Å3 (c) Assuming that the atoms are spheres and the radius of each sphere is 1.35 Å, what is the volume of one atom in Å3? (Vsphere = 4/3πr3.) WebAssign will check your answer for the correct number of significant figures. Å3 (d) Therefore, what volume of atoms are in one unit cell? WebAssign will check your answer for the correct number of significant figures. Å3 (e) Based on your results from parts (b) and (d), what is the packing efficiency of the solid expressed as a percentage?

Which statement is usually true about the relationship between activation energy and reaction rates? low activation energy barriers result in low rates. high activation energy barriers result in low rates. low activation energy barriers result in no reaction. high activation energy barriers result in no reaction.

11. phosphorus-32 is radioactive and has a half life of 14 days. how much of a 124 mg sample of phosphorus-32 is present after 56 days? a) 7.75 mg b) 15.5 mg c) 31.0 mg d) 62.0 mg

Experiment: effect of solution concentration on reaction rate you have learned that as the concentration of reactants increases, there will most likely be a greater number of collisions, and hence increase the rate of a reaction. in this experiment, you will see a demonstration of this, with a twist. there will be three reactions going on in this experiment. objectives determine how solution concentration can affect the rate of a reaction. the first reaction will be a reaction of the iodide ion (i-1) with hydrogen peroxide (h2o2) in an acidic solution. this reaction produces a slightly orange solution. in our experiment, we will add some orange food coloring to make this solution more orange. 2 h+ (aq) + 2 i- (aq) + h2o2 (aq) ⟶ i2 (aq) + 2 h2o (l) the next reaction will be between the iodine and starch i2 + starch ⟶ i2-starch complex (blue-black) so, when starch is added to the iodine solution made from the first reaction, the solution will turn black immediately, so it is difficult to find the rate of reaction. in order to be able to time this reaction, you will slow it down with another reaction. adding ascorbic acid will react with the iodine, reducing the concentration of the iodine available to react with the starch. c6h8o6 (aq) + i2 (aq) ⟶ 2i- (aq) + c6h6o6 (aq) + 2 h+ (aq) when the ascorbic acid is used up, the remaining iodine molecules can react with the starch and form the black color. the more ascorbic acid you add, the slower the reaction to form the iodine-starch complex will be. use your data and observations to complete the assignment. analysis and conclusions submit your data and the answers to these questions in the essay box below. what was your hypothesis? plot your data as drops of ascorbic acid vs. time. as the concentration of ascorbic acid was increased, did the rate of the formation of the iodine-starch complex increase or decrease? explain your answer in terms of the chemical reactions involved. was your hypothesis correct? make a general rule about the effects of concentration of reactants on reaction rates. for practice, the molecular formula for ascorbic acid is c6h8o6, and you used 6 g in this experiment, calculate the molarity of the ascorbic acid. now calculate the concentration in moles per drop (assume 1 ml = 20 drops).