Please help show work need asap thanks

Can someone me with 3 and 4 plz. this is for masteries test.

For the reaction i2(g)+br2(g)←−→2ibr(g), kc=280 at 150 ∘c. suppose that 0.450 mol ibr in a 2.00-l flask is allowed to reach equilibrium at 150 ∘c. what is the equilibrium concentration of 2ibr, i2, br2

Two changes are described below. a green banana turns yellow and ripens. a layer of rust forms on an iron nail. which statement is true about the two changes? a) both are chemical changes because new substances are formed. b) both are physical changes because only the physical state of the substances change. c) a is a physical change due to a change of state, but b is a chemical change because new molecules are formed. d) a is a chemical change due to a change of state, but b is a physical change because new molecules are formed.