Equal masses of five unknown non-electrolytes are dissolved in water and the boiling point elevations are measured. Rank the following non-electrolytes from highest to lowest molar mass. A. Boiling point of D (aq) = 103.2 degree C
B. Boiling point of A (aq) = 102.4 degree C
C. Boiling point of E (aq) = 101.3 degree C
D. Boiling point of B (aq) = 101.9 degree C
E. Boiling point of C (aq) = 100.5 degree C

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answer: the value of enthalpy change will be -152.80 kj.

solution:

pressure = 1atm , temperature = = 298 k

given that pressure and temperature are same in both gases , the number of moles of both gases can be determined by the ideal gas equation.

according to reaction 3 moles no are reacting with 1 mol of ,then 0.49 mol of no will react with moles of ozone that is 0.16 moles of ozone. since, no is limiting reagent and is an excessive reagent.

enthalpy change for the reaction between the given volumes of the gases is :