The first law of thermodynamics defines chemical energy. defines entropy. is a statement of conservation of energy. provides a criterion for the spontaneity of a reaction.

The first law of thermodynamics is a statement of conservation of energy.

Explanation:

According to the first law of thermodynamics, heat provided to a system is actually the sum of internal energy and work done by the system or on the system.

Mathematically,

The first law of thermodynamics also means that energy can neither be created nor it can be destroyed. Hence, energy is conserved.

Thus, we can conclude that the first law of thermodynamics is a statement of conservation of energy.

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