Halogenated compounds are particularly easy to identify by their mass spectra because chlorine and bromine occur naturally as mixtures of two abundant isotopes. Chlorine occurs as 35Cl (75.8%) and 37Cl (24.2%); Bromine occurs as 79Br (50.7%) and 81Br (49.3%); Boron compounds also stand out owing to the two isotopes 10B (19.9%) and 11B (80.1%). Required:
For the compound Chlorocyclohexane, C6H11Cl: At what masses do the molecular ions occur?

here we have to get the change of moles on decrease the volume of the reaction in gas phase.

the   per the given options it will decrease by (d) 11-50%

we know, on decreasing the volume of the gas phase reaction the reaction moves to the product side.

the reaction:                     so₂cl₂ (g) = so₂ (g) + cl₂ (g)         total

the moles at equilibrium:   1 - α                 α               α           = 1+α

concentrations:                   1 - α               α               α           = 1 + α

(concentration = moles/volume, as volume is 1 l)

(where α is the degree of dissociation)

now the dissociation constant in terms of concentration is :

=  

or,

or,   = (at v = 1l)

the reaction:                     so₂cl₂ (g) = so₂ (g) + cl₂ (g)         total

the moles at equilibrium:   1 - α                 α               α           = 1+α

concentrations:               (1 - α)/0.5           α/0.5         α/0.5       = (1 + α)/0.5

thus, the dissociation constant in terms of concentration is :

or,  

=  

so, the change of 1 : 1/0.5

or, 1: 2

thus it will decrease by 50%.

or, as per the given options it will decrease by 11-50%

elements make up everything, and they combine to make compounds.

the answer is c