Why the energy difference between the removal of the 2nd and 3rd electrons is smaller than that between the removal of the 3rd the 4th electrons ?

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a). in this case, dh> 0 and sd> 0. if t becomes larger, the term "-tds" will become more negative. at some point, it is possible that -dts will be more negative than the dh is positive, and the reaction will become spontaneous. this is probably the correct answer, but you should look at all of the other possibilities and make sure of that.