Replicate water samples are analyzed for water hardness with the following results: 102.2, 102.8, 103.1 and 102.5ppm CaCO3. Calculate:-
(a) The standard deviation
(b) The relative standard deviation
(c) The standard deviation of the mean
(d) The relative standard deviation of the mean.

1. for the first question, we must find the mass of the anhydrous salt, mgso₄. the molar mass for mgso₄·7h₂o is 246.47 g/mol, while that of mgso₄ is 120.37 g/mol.7.834 g mgso₄·7h₂o * 1 mol mgso₄·7h₂o/246.47 g * 1 mol mgso₄/1 mol mgso₄·7h₂o * 20.37 g mgso₄/mol = 0.647 g mgso₄

2. mass of water = mass of sample - mass of anhydrous salemass of water = 7.834 - 0.647 = 7.19 gpercent water in hydrate = 7.19/7.834 * 100 = 91.74%

warm front forms when a moist, warm air mass slides up and over a cold air mass. as the warm air mass rises, it condenses into a broad area of clouds. a warm front brings gentle rain or light snow, followed by warmer, milder weather.

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