A solution is prepared by dissolving 0.23 mol of hypochlorous acid and 0.27 mol of sodium hypochlorite in water sufficient to yield 1.00 L of solution. The addition of 0.05 mol of HCl to this buffer solution causes the pH to drop slightly. The pH does not decrease drastically because the HCl reacts with the present in the buffer solution. The Ka of hypochlorous acid is 1.36 × 10-3.

hypochlorite ion

Explanation:

The hypochlorous acid, HClO, is a weak acid with Ka = 1.36x10⁻³, when this acid is in solution with its conjugate base, ClO⁻ (From sodium hypochlorite, NaClO) a buffer is produced. When a strong acid as HCl is added, the reaction that occurs is:

HCl + ClO⁻ → HClO + Cl⁻.

Where more hypochlorous acid is produced.

That means, the HCl reacts with the hypochlorite ion present in solution

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