In thermal equilibrium problems when comparing the two systems water and a hot ball of iron, which system is negative when using the formula ms(Delta T) = -ms(Delta T)?​

Given sno2 + 2h2 - sn + 2h20 tin oxide reacts with hydrogen to produce tin and water. how many moles of sno2 are needed to produce 500.0 grams of sn?

If anyone would be able to me out with these three questions it would be these are from the chem 2202 course.

The content of manganese (mn) in steel was determined spectrophotometrically and with the use of the standard addition method. an unknown sample of mn from a digested steel sample gave an absorbance of 0.185 when analyzed spectrophotometrically. when 5.00 ml of solution containing 95.5 ppm mn was added to 50.0 ml of the unknown steel solution (digested sample), the absorbance was 0.248. calculate the concentration, in parts-per-million (ppm), of mn in the digested steel sample solution.