Match each definition to the appropriate term. The extent of randomness in a system
Sum of the internal energy plus the product of the pressure and volume for a reaction
Difference of the enthalpy (of a system) minus the product of the entropy and absolute temperature
The condition that a reaction takes place without outside help
Solution in which no more solute can be dissolved in the solvent

possibly, yes.

explanation:

the amount of sugar you take in is dangerously high, risk of heart disease, high risk of diabetes, and etc.

hydrocarbons are organic compounds that contain only hydrogens and carbons. they can be saturated (those which contain only carbon-carbon single bonds) or unsaturated (those which contain carbon-carbon double or triple bonds) in nature. hydrocarbons can undergo several reactions like substitution, elimination etc.  

on substituting one or more hydrogen atoms in hydrocarbon it results in the formation of haloalkane. as the halogen atoms are large compared to the carbon and hydrogen atoms, due to which the molecular weight increases and the bond become polar because of presence electronegative halogen atom and results in the increase in boiling point of the haloalkane.

thus, the correct option is (b) that is the boiling point of the new compound increases on substituting a hydrogen atom with a halogen in a hydrocarbon.