How did the idea of what a cell was develop overtime​

Achemist wants to extract copper metal from copper chloride solution. the chemist places 0.50 grams of aluminum foil in a solution containing 0.75 grams of copper (ii) chloride. a single replacement reaction takes place. (ii) chloride. a single replacement reaction takes place. which statement explains the maximum amount of copper that the chemist can extract using this reaction? a) approximately 0.36 grams, because copper (ii) chloride acts as a limiting reactant b) approximately 1.8 grams, because copper (ii) chloride acts as a limiting reactant c) approximately 0.36 grams, because aluminum acts as a limiting reactant d) approximately 1.8 grams, because aluminum acts as a limiting reactant

If anyone would be able to me out with these three questions it would be these are from the chem 2202 course.

Consider the following reaction at equilibrium: c(s)+h2o(g)⇌co(g)+h2(g) predict whether the reaction will shift left, shift right, or remain unchanged upon each of the following disturbances. a) c is added to the reaction mixture. b) h2ois condensed and removed from the reaction mixture c) co is added to the reaction mixture d) h2 is removed from the reaction mixture.