The iridium(IV)hexachloride anion reacts with triphenylphosphine in diethylene glycol under an atmosphere of CO to give Vaska’s compound (Compound A). Addition of excess carbon monoxide produces a five-coordinate species (Compound B). Treatment of B with NaBH4 in ethanol gives Compound C. (i) Draw the structures of the three complexes. (Show metal stereocentres)
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The iridium(IV)hexachloride anion reacts with triphenylphosphine in diethylene glycol under an atmos...
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