1. Which of the following will dissolve the most in water? a) CH3CH2CH2CH2OH b) CH3CH2OH

2. Which of the following will dissolve the most in water?

a) CCl4 b) CaCl2

3. Which of the following will dissolve the most in water?

a) benzene, C6H6 b) phenol, C6H5OH

4. Which of the following will be more soluble in hexane, C6H14?

a) cyclohexane, C6H12 b) glucose

5. Which of the following will be more soluble in hexane, C6H14?

a) propionic acid, CH3CH2COOH b) CH3CH2COONa

6. Which of the following will be more soluble in hexane, C6H14?

a) HCl b) CH3CH2Cl

hydrocarbons are organic compounds that contain only hydrogens and carbons. they can be saturated (those which contain only carbon-carbon single bonds) or unsaturated (those which contain carbon-carbon double or triple bonds) in nature. hydrocarbons can undergo several reactions like substitution, elimination etc.  

on substituting one or more hydrogen atoms in hydrocarbon it results in the formation of haloalkane. as the halogen atoms are large compared to the carbon and hydrogen atoms, due to which the molecular weight increases and the bond become polar because of presence electronegative halogen atom and results in the increase in boiling point of the haloalkane.

thus, the correct option is (b) that is the boiling point of the new compound increases on substituting a hydrogen atom with a halogen in a hydrocarbon.

intermolecular forces are the forces between molecules or particles.

there are two kinds of van der waals forces: weak london dispersion forces and stronger dipole-dipole forces.

in molecule of water there are dipole-dipole forces between negatively charged oxygen from one molecule of water and positively charger hydrogen of another molecule of water.

hydrogen bond is an electrostatic attraction between two polar groups that occurs when a hydrogen atom (h), covalently bound to a highly electronegative atom such as flourine (f), oxygen (o) and nitrogen (n) atoms.