Anybody know chemistry Grahams law ?

There is two different types but i’ll just do both meanings just incase.

Graham's Law of Diffusion: the rate of diffusion of one gas through another is inversely proportional to the square root of the density of the gas.

Graham's Law of Effusion: the rate of effusion of a gas is inversely proportional to the square root of the density of the gas.

hopes this helps..!

I’m not sure what your trying to say here.. can you clarify again?

The problem here is that according to aufbau principle before 3d orbital 4s subshell comes.after filling 3p orbital with electrons you have 4 electrons left, you place two in 4s with opposite spin and the other two in 3d in any of its two orbitals of total five orbitals with the same spin.