HANG IN THERE, BREATHE DEEP, BE CALM AND STICK IT! YOU CAN DO IT DON'T GIVE UP. can someone give it a explaination? pls i need this tommorow

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Two nitro no2 groups are chemically bonded to a patch of surface. they can't move to another location on the surface, but they can rotate (see sketch at right). it turns out that the amount of rotational kinetic energy each no2 group can have is required to be a multiple of ε, where =ε×1.010−24 j. in other words, each no2 group could have ε of rotational kinetic energy, or 2ε, or 3ε, and so forth — but it cannot have just any old amount of rotational kinetic energy. suppose the total rotational kinetic energy in this system is initially known to be 32ε. then, some heat is removed from the system, and the total rotational kinetic energy falls to 18ε. calculate the change in entropy. round your answer to 3 significant digits, and be sure it has the correct unit symbol.

Salicylic acid is a very important acid. it is used to synthesize the aspirin by treating with acetic anhydride. a 0.2015-g sample of salicylic acid was dissolved in a 100.00-ml volumetric flask, and the solution was diluted to the mark. a 10-ml aliquot of this solution was titrated with standard naoh (0.01130 + 0.2% n) to a phenolphthalein faint pink color end point at 19.81 ml. (a) (calculate the normality of the salicylic acid solution used in the titration. (b) assuming the salicylic acid is pure, what is the equivalent weight of the salicylic acid? practice problems for the final exam (continued) (c) (calculate the inherent error in the determination of the equivalent weight you calculated in part (b). use the following absolute errors in the equipment /glassware when calculating the inherent error. 5.00-ml pipet: + 0.02 ml 100-ml volumetric flask: + 0.08 ml analytical balance: + 0.2 mg 25-ml buret: + 0.03 ml