At STP, a 12.0-liter sample of CH4(g) has the same total number of molecules as

A) 6.0 L of H2(g) at STP

B) 12.0 L of CO2(g) at STP

C) 18.0 L of HCl(g) at STP

D) 24.0 L of O2(g) at STP

answer : (a) volume of the gas = 8.67 ×   l

                (b) second virial coefficient b = -1.21226 l/mole

solution :   given,     t = 300k

                                p = 20atm

                                z = 0.86

                                n = 8.2 mmoles = 8.2 × moles

                                r =   0.082 l atm/k/mol

        find,     (a) volume of gas   and (b) second virial coefficient b at 300k.

formula used :            

                          and            

(a)            

                    = \times 0.082\times 300}{20}[/tex]

                    = 8.67 ×   l

(b)      

                    = (0.00867-1) × 8.659

                    = - 8.5839 l/mole