Why values from mean bond enthalpy calculations differ from hess cycle

1. a)c-14 has two more protons

2. d)they have different numbers of protons, neutrons, and valence electrons; they are all gases at room temperature.

3. c) iron and nickel.

c is having 4 valence electrons and is bonded to three hydrogens and one sulphur atom, therefore, the number of bond pair is equal to four. as all the valence electrons are used in forming the bonds so, there is no lone pair left on carbon.

s is having 6 valence electrons and is bonded to one other sulfur atom and one carbon atom, therefore, the number of bond pair is equal to 2. as only two valence electrons are used in forming the bonds so, four electrons are left. therefore, two lone pairs are present on s.

answer: semi-infinite solid initially at a uniform temperature of 400 ◦c is cooled at its surface by convection. the cooling fluid at a constant temperature of 200 ◦c has a convective coefficient (ha) of 250 w/m2.k. the physical properties of the solid: k = 20 w/m.k and α = 4 * 10-5  m2/s. using δx = 0.04 m and δt = 10 s. write the finite difference equations describing the transient heat transfer of the first five δx and the temperature profile after 30 s.