Each time the boy breathes, he exhales 0.02231 moles of gas at STP. How many liters of gas does he exhale?

Yes you are correct use the scientific method

It is a mixture. simply put, a compound must be pure, that is, of only one chemical structure and composition. a mixture is made of different chemical substances (i.e. elements, molecules, compounds) that are not chemically bonded to each other, but instead physically grouped together, as in the case of gasoline (a homogeneous solution).

Vander waals forces are inter molecular bonds that exist within molecules of the same substance. a water molecule is made up of oxygen and hydrogen atoms which share electrons between each other. the vander waals forces are forces that exist between multitude of different  molecules of water. dipole dipole forces is the type of vander waals force that exist in water. the oxygen atom which is more electronegative pulls the shared electron closer to itself thus generating a partial negative charge while the hydrogen acquire a partial positive charge. these two different charges causes attraction to occur in water molecules.