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hydrocarbons are organic compounds that contain only hydrogens and carbons. they can be saturated (those which contain only carbon-carbon single bonds) or unsaturated (those which contain carbon-carbon double or triple bonds) in nature. hydrocarbons can undergo several reactions like substitution, elimination etc.  

on substituting one or more hydrogen atoms in hydrocarbon it results in the formation of haloalkane. as the halogen atoms are large compared to the carbon and hydrogen atoms, due to which the molecular weight increases and the bond become polar because of presence electronegative halogen atom and results in the increase in boiling point of the haloalkane.

thus, the correct option is (b) that is the boiling point of the new compound increases on substituting a hydrogen atom with a halogen in a hydrocarbon.

the term hydride is commonly named after binary compounds that hydrogen forms with other elements of the periodic table. hydride compounds in general form with almost any element, except a few noble gases. the trends and properties vary according to the type of intermolecular force that bonds the elements together, the temperature, its molecular masses, and other components. hydrides are classified into three major groups, depending on what elements the hydrogen bonds to. the three major groups are covalent, ionic, and metallic hydrides. formally, hydride is known as the negative ion of a hydrogen, h-, also called a hydride ion. because of this negative charge, hydrides have reducing, or basic properties. its special characteristics will be further discussed.

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