Please answer this if you do I will answer your questions!!

When will le chatelier's principle come into effect? at the beginning of a reaction, when there are only reactants when a reaction has reached chemical equilibrium when a catalyst is added to a reaction mixture when a reaction is occurring but not yet at equilibrium

What is the lowest number energy level where a d sublevel is found

For the reaction c6h14(g) & longrightarrow; c6h6(g) + 4h2(g), δp(h2)/δt was found to be 2.5 x 10-2 atm/s, where δp(h2) is the change in pressure of hydrogen. determine δp(c6h14)/δt for this reaction at the same time.