Please help me with these questions please

An exothermic reaction is conducted in an insulated calorimeter filled with water. the calorimeter is then sealed so that there is no heat exchanged between the contents of the container and the surrounding air. which of the following statements is true about the reaction?

1. if you have a gas at 127 degrees c, what is it's absolute temperature (kelvin)? a. 200kb. 300kc. 400kd. 500k2. if you had a gas whose absolute temperature measured 45 k, what is that temperature in celsius? a. -228 cb. -300 cc. 125 cd. 112 c

8. what happens to matter during a chemical reaction