Please help me with this 2 answers i will give brainliest to the more good answer

How many mmols of tris-hcl are there in 100 ml of a 100 mm tris-hcl buffer solution at ph 8.1? note that the 100 mm refers to the sum of tris and tris-hcl concentrations?

Find the number of grams of hcl needed to react completely with .50 moles of magnesium.

4.25g sample of solid ammonium nitrate dissolves in 60.0g of water in a coffee-cup calorimeter, the temperature drops from 22.0 c to 16.9 c. assume that the specific heat of the solution is the same as that of pure water. calculate delta(h) (in kj/mol nh4no3) for the solution proces.