I need help with these 2 chemistry problems, fairly simple just forgot. Due in 5 minutes please help thank you! (Hurry) <3

Harvey kept a balloon with a volume of 348 milliliters at 25.0˚c inside a freezer for a night.  when he took it out, its new volume was 322 milliliters, but its pressure was the same.  if the final temperature of the balloon is the same as the freezer’s, what is the temperature of the freezer? the temperature of the freezer is  kelvins.

Base your answer on the information below and on your knowledge of chemistry. nitrogen dioxide, no2, is a dark brown gas that is used to make nitric acid and to bleach flour. nitrogen dioxide has a boiling point of 294 k at 101.3 kpa. in a rigid cylinder with a movable piston, nitrogen dioxide can be in equilibrium with colorless dinitrogen tetroxide, n2o4. this equilibrium is represented by the equation below. 2no2(g) n2o4(g) + 58kj at standard pressure, compare the strength of intermolecular forces in no2(g) to the strength of intermolecular forces in n2(g).

Gwhich r group would most likely be found in a hydrophobic area of the tertiary structure of a globular protein? which r group would most likely be found in a hydrophobic area of the tertiary structure of a globular protein? −ch2−oh −ch2−o||c−nh2 −ch2−coo− −ch2−ch2−ch2−ch2−n+h3