Is the formation of the grand canyon a physical or chemical change

A32 year old immigrant from a patriarchal country is giving birth. as she is delivering the baby, she tearfully confesses to her doctor that this is her 4th child and she simply cannot handle any more children. she tells the doctor that her husband refuses to use contraception or allow her to, and she begs her doctor to tie her tubes and not tell her husband. the doctor complies. was hipaa violated? why or why not?

Calculate the expected ph values of the buffer systems from the experiments (a,b,c,d), using the henderson- hasselbalch equation, ph-pka+log[a-]/[ha]. use for pka values carbonic acid= 6.37, and acetic acid= 4.75.

When 225mg of anthracene, c14h10(s), was burned in a bomb calorimeter the temperature rose by 1.75k. calculate the calorimeter constant. by how much will the temperature rise when 125mg of phenol, c6h5oh(s), is burned in the calorimeter under the same conditions? (δch< (c14h10,s)=–7061 kj mol−1.)