Two solutions, initially at 24.60 °C, are mixed in a coffee cup calorimeter (Ccal = 15.5 J/°C). When a 100.0 mL volume of 0.100 M AgNO3 solution is mixed with a 100.0 mL sample of 0.200 M NaCl solution, the temperature in the calorimeter rises to 25.30 °C. Determine the ∆H°rxn in kJ/mol AgCl for the reaction as written below. The density of the final solution is 1.00 g/mL and heat capacity of the final solution is 4.18 J/goC. NaCl(aq) + AgNO3(aq) → AgCl(s) + NaNO3(aq) H°rxn= ?

ΔH = -59.6kJ/mol

Explanation:

The reaction that occurs between Ag⁺ and Cl⁻ ions is:

Ag⁺ + Cl⁻ → AgCl(s) + ΔH

To find ΔH we need to obtain moles of reaction and heat released in the reaction because ΔH is defined as heat released per mole of reaction.

Moles of reaction:

Moles of Ag⁺ and Cl⁻ added are:

Ag⁺: 0.100L * (0.100mol / L) = 0.01moles

Cl⁻: 0.100L * (0.200mol / L) 0 0.02 moles

That means limiting reactant is Ag⁺ and moles of reaction are 0.01 moles

Heat released:

To find heat released we must use coffe cup calorimeter equation:

Q = C*m*ΔT

Where C is specific heat of solution (4.18J/g°C), m is the mass of solution (200g because there are 100 + 100mL = 200mL and density of solution is 1g/mL) and ΔT is change in temperature (25.30°C - 24.60°C = 0.70°C).

Replacing:

Q = C*m*ΔT

Q = 4.18J/g°C * 200g * 0.70°C

Q = 585,2J

Is total heat released.

The calorimeter absorbs:

15.5J / °C * 0.7°C = 10.85

Thus, when 0.01 moles reacts, 585.2J + 10.85  = 596.05J are released (Heat released is heat abosrbed by calorimeter + Heat absorbed by water) and ΔH is:

ΔH = 596.05J / 0.01 moles =

ΔH = 59605J / mol =

As heat is released, ΔH < 0.

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