A compound is found to contain 18.28 % phosphorus , 18.93 % sulfur , and 62.78 % chlorine by mass. To answer the question, enter the elements in the order presented above. QUESTION 1: The empirical formula for this compound is . QUESTION 2: The molar mass for this compound is 169.4 g/mol. The molecular formula for this compound is

1. EF = PSCl₃; 2. MF = PSCl₃  

Explanation:

1. Empirical formula

The empirical formula is the simplest whole-number ratio of atoms in a compound.

The ratio of atoms is the same as the ratio of moles.

So, our first job is to calculate the molar ratio of P:S:Cl.

Assume 100 g of the compound.

(a) Calculate the mass of each element.

Then we have 18.28 g P, 18.93 g S, and 67.28 g Cl.

(b) Calculate the moles of each element

(c) Calculate the molar ratio of the elements

Divide each number by the smallest number of moles

P:S:Cl = 0.5902:0.5905:1.898 = 1:1.000:3.000 ≈ 1:1:3

(d) Write the empirical formula

EF = PSCl₃

The empirical formula for this compound is PSCl₃.

2. Molecular formula

(a) Calculate the ratio of the molecular and empirical formula masses

n = (169.4 u)/(169.40 u) = 1.000 ≈ 1

(b) Calculate the molecular formula

MF = (EF)ₙ = (EF)₁ = PSCl₃

The molecular formula for this compound is PSCl₃.

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